Supplementary material from "Towards implementing hierarchical porous zeolitic imidazolate frameworks in dye-sensitized solar cells"
Posted on 2019-06-18 - 11:40
A one-pot method for encapsulation of dye, which can be applied for dye-sensitized solar cells (DSSCs), and synthesis of hierarchical porous zeolitic imidazolate frameworks (ZIF-8), is reported. The size of the encapsulated dye tunes the mesoporosity, and surface area of ZIF-8. The mesopore size, Langmuir surface area and pore volume are 15 nm, 960–1500 m2 · g−1 and 0.36–0.61 cm3 · g−1, respectively. After encapsulation into ZIF-8, the dyes show longer emission lifetimes (greater than 4–8 fold) as compared to the corresponding non-encapsulated dyes, due to suppression of aggregation, and torsional motions.
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Abdelhamid, Hani Nasser; El-Zohry, Ahmed M.; Cong, Jiayan; Thersleff, Thomas; Karlsson, Martin; Kloo, Lars; et al. (2019). Supplementary material from "Towards implementing hierarchical porous zeolitic imidazolate frameworks in dye-sensitized solar cells". The Royal Society. Collection. https://doi.org/10.6084/m9.figshare.c.4545650.v1