Supplementary material from "Pyroelectricity and field-induced spin-flop in (4-(Aminomethyl)pyridinium)2MnCl4·2H2O"
Posted on 2020-05-16 - 04:39
Large single crystals of (4-(Aminomethyl)pyridinium)2MnCl4·2H2O (1) were grown by slow evaporation of solution. The crystal structure was solved to be Pī, which belongs to the central symmetric space group. But small pyroelectric current was detected, as well as a ferroelectric hysteresis loop. The pyroelectric and the ferroelectric properties were attributed to the strain caused by defects. Temperature-dependent magnetic curves and the M–H curve shows that 1 is antiferromagnetic ordering below 2.5 K. A field-induced spin-flop is observed in the antiferromagnetic ordering state.
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Gao, Kaige; Liu, Chunlin; Zhang, Wei; Wang, Kangni; Liu, Wenlong (2020). Supplementary material from "Pyroelectricity and field-induced spin-flop in (4-(Aminomethyl)pyridinium)2MnCl4·2H2O". The Royal Society. Collection. https://doi.org/10.6084/m9.figshare.c.4981400
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AUTHORS (5)
KG
Kaige Gao
CL
Chunlin Liu
WZ
Wei Zhang
KW
Kangni Wang
WL
Wenlong Liu